103 |
|
(4\%) initial rise in $\theta_{J}$ as a function of particle |
104 |
|
anisotropy. However, the jamming limit {\it decreases} with |
105 |
|
increasing particle anisotropy once the length-to-breadth ratio rises |
106 |
< |
above 2. I.e. ellipsoids landing randomly on a surface will, in |
106 |
> |
above 2, \emph{i.e.}~ellipsoids landing randomly on a surface will, in |
107 |
|
general, cover a smaller surface area than disks. Randomly thrown thin |
108 |
|
lines cover an even smaller area.\cite{Viot1992b} |
109 |
|
|
110 |
|
How, then, can one explain a near-monolayer coverage by the umbrella |
111 |
< |
molecules? There are really two approaches, one static and one |
112 |
< |
dynamic. In this paper, we present a static RSA model with {\em |
111 |
> |
molecules? In this paper, we present a static RSA model with {\em |
112 |
|
tilted} disks that allows near-monolayer coverage and which can |
113 |
|
explain the differences in coverage between the octopus and umbrella. |
114 |
|
In section \ref{rsaSec:model} we outline the model for the two adsorbing |
218 |
|
was then checked for intersection with both of the umbrella tops. If |
219 |
|
the line did indeed intersect the tops, then the points of |
220 |
|
intersection along the line were checked to insure sequential |
221 |
< |
intersection of the two tops. ie. The line most enter then leave the |
221 |
> |
intersection of the two tops. ie. The line must enter then leave the |
222 |
|
first top before it can enter and leave the second top. These series |
223 |
|
of tests were demanding of computational resources, and were therefore |
224 |
|
only attempted if the original handle - projection overlap test had |
231 |
|
|
232 |
|
For the on-lattice simulations, the initially chosen location on the |
233 |
|
plane was used to pick an attachment point from the underlying |
234 |
< |
lattice. I.e. if the initial position and orientation placed one of |
234 |
> |
lattice. Meaning, if the initial position and orientation placed one of |
235 |
|
the thiol legs within a small distance ($\epsilon = 0.1 \mbox{\AA}$) |
236 |
|
of one of the interstitial attachment points, the lander was moved so |
237 |
|
that the thiol leg was directly over the lattice point before checking |
273 |
|
larger gold surface. |
274 |
|
|
275 |
|
Once the system is constrained by the underlying lattice, $\theta_{J}$ |
276 |
< |
drops to 0.5378, showing that the lattice has an almost |
276 |
> |
drops to 0.5378, showing that the lattice has an |
277 |
|
inconsequential effect on the jamming limit. If the spacing between |
278 |
|
the interstitial sites were closer to the radius of the landing |
279 |
|
particles, we would expect a larger effect, but in this case, the |
378 |
|
Table \ref{rsaTab:coverage}. |
379 |
|
|
380 |
|
\begin{table} |
381 |
< |
\caption[RSA experimental comparison]{RATIO OF MONOLAYER SULFUR ATOMS TO GOLD SURFACE ATOMS} |
381 |
> |
\caption{RATIO OF MONOLAYER SULFUR ATOMS TO GOLD SURFACE ATOMS} |
382 |
|
\label{rsaTab:coverage} |
383 |
|
\begin{center} |
384 |
|
\begin{tabular}{|l|l|l|} |