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\begin{document} |
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\title{Simulating Interfacial Thermal Conductance at Metal-Solvent |
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Interfaces: the Role of Chemical Capping Agents} |
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\author{Shenyu Kuang and J. Daniel |
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Gezelter\footnote{Corresponding author. \ Electronic mail: gezelter@nd.edu} \\ |
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Department of Chemistry and Biochemistry,\\ |
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University of Notre Dame\\ |
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Notre Dame, Indiana 46556} |
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\date{\today} |
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\maketitle |
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\begin{doublespace} |
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\newpage |
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%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% |
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% BODY OF TEXT |
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%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%% |
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\begin{table*} |
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\begin{minipage}{\linewidth} |
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\begin{center} |
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\caption{In the hexane-solvated interfaces, the system size has |
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little effect on the calculated values for interfacial |
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conductance ($G$ and $G^\prime$), but the direction of heat |
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flow (i.e. the sign of $J_z$) can alter the average |
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temperature of the liquid phase and this can alter the |
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computed conductivity.} |
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\begin{tabular}{ccccccc} |
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\hline\hline |
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$\langle T\rangle$ & $N_{hexane}$ & $\rho_{hexane}$ & |
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$J_z$ & $G$ & $G^\prime$ \\ |
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(K) & & (g/cm$^3$) & (GW/m$^2$) & |
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\multicolumn{2}{c}{(MW/m$^2$/K)} \\ |
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\hline |
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200 & 266 & 0.672 & -0.96 & 102(3) & 80.0(0.8) \\ |
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& 200 & 0.688 & 0.96 & 125(16) & 90.2(15) \\ |
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& & & 1.91 & 139(10) & 101(10) \\ |
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& & & 2.83 & 141(6) & 89.9(9.8) \\ |
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& 166 & 0.681 & 0.97 & 141(30) & 78(22) \\ |
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& & & 1.92 & 138(4) & 98.9(9.5) \\ |
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\hline |
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250 & 200 & 0.560 & 0.96 & 75(10) & 61.8(7.3) \\ |
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& & & -0.95 & 49.4(0.3) & 45.7(2.1) \\ |
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& 166 & 0.569 & 0.97 & 80.3(0.6) & 67(11) \\ |
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& & & 1.44 & 76.2(5.0) & 64.8(3.8) \\ |
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& & & -0.95 & 56.4(2.5) & 54.4(1.1) \\ |
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& & & -1.85 & 47.8(1.1) & 53.5(1.5) \\ |
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\hline\hline |
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\end{tabular} |
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\label{AuThiolHexaneUA} |
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\end{center} |
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\end{minipage} |
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\end{table*} |
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\begin{table*} |
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\begin{minipage}{\linewidth} |
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\begin{center} |
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\caption{When toluene is the solvent, the interfacial thermal |
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conductivity is less sensitive to temperature, but again, the |
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direction of the heat flow can alter the solvent temperature |
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and can change the computed conductance values.} |
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|
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\begin{tabular}{ccccc} |
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\hline\hline |
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$\langle T\rangle$ & $\rho_{toluene}$ & $J_z$ & $G$ & $G^\prime$ \\ |
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(K) & (g/cm$^3$) & (GW/m$^2$) & \multicolumn{2}{c}{(MW/m$^2$/K)} \\ |
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\hline |
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200 & 0.933 & 2.15 & 204(12) & 113(12) \\ |
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& & -1.86 & 180(3) & 135(21) \\ |
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& & -3.93 & 176(5) & 113(12) \\ |
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\hline |
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300 & 0.855 & -1.91 & 143(5) & 125(2) \\ |
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& & -4.19 & 135(9) & 113(12) \\ |
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\hline\hline |
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\end{tabular} |
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\label{AuThiolToluene} |
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\end{center} |
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\end{minipage} |
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\end{table*} |
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\end{doublespace} |
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\end{document} |
